Macrocyclic dinuclear copper(II) complex with a novel chloride bridged zigzag chain

作者：Lu, TB^*; Chen, S; Mao, ZW; Martell, AE; Ji, LN

来源：Inorganic Chemistry Communications, 2003, 6(8): 1068-1070.

DOI：10.1016/S1387-7003(03)00195-3

• macrocyclic dinuclear copper complex
• ID chain
• bridging chloride
• folded chair conformation

A macrocyclic dinuclear copper complex Cu2LCl(ClO4).H2O, where L = 15,31-dimethyl-3,11,19,27,33,35-hexaazapentacyclo[27.3.1.1.(5;9)1(13;17)1.(21,25)]-hexatriaconta-5,7,9(33),13,15,17(34),21,23,25(35),29,31,1(36)-dodecaene-34,36-diol, has been synthesized and characterized by single-crystal X-ray diffraction. In the complex, each Cu(II) ion is coordinated with three macrocyclic nitrogen atoms and one phenolate oxygen anion. The dinuclear copper complexes are linked by the bridged Cl- to form a novel zigzag chain with a folded chair conformation.

• 出版日期2003-8
• 单位中山大学