摘要

Local equilibrium theory has long been employed to explain the thermodynamics and kinetics of proeutectoid ferrite transformation in Fe-C-X systems. The growth kinetics of proeutectoid ferrite is decided by the diffusion behavior of the alloy element X during transformation. One of the key issues in application of this theory is the theoretical calculation and experiment determination of the partitional local equilibrium/negligible partitional local equilibrium boundary (PLENPLE transition temperature). In this study, we developed a simple analytic method to calculate the PLENPLE boundary. With this method, the PLE/NPLE boundaries in Fe - C - Mn and Fe - C - Ni systems are successfully computed and the results agree well with the formerly reported experimental results.