Acetonitrile{3-[bis(2-pyridylmethyl-kappa N)amino-kappa N]propanol-kappa O}(perchlorato-kappa O)copper(II) perchlorate

作者：Shin Jong Won; Rowthu Sankara Rao; Cho Hyun Jung; Min Kil Sik^*

来源：Acta Crystallographica Section E-Structure Reports Online, 2011, 67: M143-U350.

DOI：10.1107/S1600536810053985

In the title compound, [Cu(ClO4)(C2H3N)(C15H19N3O)]ClO4, the Cu-II ion is coordinated by three N atoms and a hydroxyl-O atom of the tetradentate ligand, an O atom of a perchlorate ion and an N atom of an acetonitrile ligand giving a tetragonally distorted octahedral environment around the copper(II) atom. There is an offset inter-complex face-to-face pi-pi interaction [centroid-centroid distance = 3.718 (2) angstrom] involving one of the pyridine rings of the ligand as well as an intra-complex O-H center dot center dot center dot O hydrogen-bonding interaction between the coordinated hydroxyl group of the ligand and the perchlorate counter-ion.

• 出版日期2011-2