Visible-Light-Mediated Reactions of Electrophilic Radicals with Vinyl and Allyl Trifluoroborates

作者:Reina Daniel Fernandez; Ruffoni Alessandro; Al Faiyz Yasair S S; Douglas James J; Sheikh Nadeem S*; Leonori Daniele*
来源:ACS Catalysis, 2017, 7(6): 4126-4130.
DOI:10.1021/acscatal.7b01120

摘要

Visible-light photoredox catalysis enables the vinylation and allylation of electrophilic radicals with readily available potassium trifluoroborate reagents. The processes show good functional group compatibility, and mechanistic and computational studies have elucidated some of the aspects associated with the key radical addition step.

  • 出版日期2017-6