科研之友
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摘要
The key features of halogenophilic reactions defining their role in organic chemistry are considered. The results of studies of mechanisms involving a nucleophilic attack at the halogen atom (S(N)2Hal) are summarized. The main mechanistic evidence comes from the studies of halogen-metal exchange reactions. Primary attention is paid to the role of halogenophilic reaction as a competing process or a concealed mechanism in ordinary nucleophilic substitution reaction at carbon atoms. The bibliography includes 249 references.
- 出版日期2012
