Unambiguous Characterization of Gunshot Residue Particles Using Scanning Laser Ablation and Inductively Coupled Plasma-Mass Spectrometry

作者：Abrego Zurine; Ugarte Ana; Unceta Nora; Fernandez Isla Alberto; Aranzazu Goicolea M; Barrio Ramon J^*

来源：Analytical Chemistry, 2012, 84(5): 2402-2409.

DOI：10.1021/ac203155r

A new method based on scanning laser ablation and inductively coupled plasma-mass spectrometry (LA-ICPMS) for the detection and identification of gunshot residue (GSR) particles from firearms discharges has been developed. Tape lifts were used to collect inorganic residues from skin surfaces. The laser ablation Laser pattern and ICPMS conditions were optimized for the detection of metals present in GSR, such as Sb-121, Ba-137, and Pb-208. Other isotopes (Al-27, Si-29, P-31, S-33, Cl-35, K-39, Ca-44, Fe-57, Ni-60, (CU)-C-63, Zn-66, and Sn-118) were monitored during the ICPMS analyses to obtain additional information to possibly classify the GSR particles as either characteristic of GSR or consistent with GSR. In experiments with real samples, different firearms, calibers, and ammunitions were used. The performed method evaluation confirms that the developed methodology can be used as an alternative to the standard scanning electron microscopy - energy dispersive spectroscopy (SEM-EDS) technique, with the significant advantage of drastically reducing the analysis time to less than 66 min.

• 出版日期2012-3-6