An intriguing 4d-4f heterometallic coordination polymer with 1D pseudo-nanotube architectures

作者：Kang Yi Fan; Liu Ping^*; Yuan Chao; Cui Lin; Liu Yang; Wang Yao Yu

来源：Inorganic Chemistry Communications, 2013, 36: 4-7.

DOI：10.1016/j.inoche.2013.07.006

• Heterometallic
• Coordination polymer
• Pseudo-nanotube
• Luminescence

A new one-dimensional (1D) 4d-4f heterometallic coordination polymer [ErAg(Himdc)(2)(H2O)(3)] (1) (H(3)imdc = 4,5-imidazoledicarboxylic acid) is synthesized under hydrothermal condition and characterized by elemental analysis, IR, PXRD and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic space group P-1, showing a 1D metal-organic pseudo-nanotube with a 4.014 x 12.027 angstrom(2) cross-section. Furthermore, it assembles into a 3D supramolecular architecture via hydrogen bonds between pseudo-nanotubes. The complex 1 exhibits solid-state photoluminescence and high thermal stability.

• 出版日期2013-10
• 单位西北大学