Preparation of 2,4,6-trisphosphinyl-1,3,5-triazine (1,3,5-triazinetriphosphonic acid)

作者：Ioannou Panayiotis V^*

来源：Main Group Chemistry, 2014, 13(2): 147-151.

DOI：10.3233/MGC-140129

• Cyanuric chloride
• tris(trimethylsilyl) phosphite
• 2,4,6-trisphosphinyl-1,3,5-triazine

The reaction of excess tris(trimethylsilyl) phosphite with cyanuric chloride produced the ester 2,4,6-trisdi(trimethylsilyloxyphosphinyl)-1,3,5-triazine. After partial purification the ester was methanolysed to the free acid 2,4,6-trisphosphinyl-1,3,5-triazine in good to excellent yields. Some properties of the acid are described.

• 出版日期2014