摘要

The octanuclear coordination cage [Ni-8(L-14Naph)(12)](BF4)(16) has the core structure of a 'cuneane' - a toplogical isomer of a cube - with a metal ion at each of the eight vertices and bridging ligand spanning each of the twelve edges; this is the only possible 8-vertex polyhedron other than a cube that will form a cage in which each metal is connected to three others.

  • 出版日期2011