A copper(II)-ethylenediamine modified polyoxoniobate with photocatalytic H-2 evolution activity under visible light irradiation

作者：Wang, Zhen-Li; Tan, Hua-Qiao; Chen, Wei-Lin^*; Li, Yang-Guang; Wang, En-Bo

来源：Dalton Transactions, 2012, 41(33): 9882-9884.

DOI：10.1039/c2dt30663h

• HYDROGEN EVOLUTION
• WATER
• OXIDATION
• NIOBATE
• DECOMPOSITION
• NANOSHEETS
• PROPERTY
• ALCOHOLS
• COMPLEX
• DRIVEN

A new dimer polyoxoniobate [Cu(en)(2)](11)K4Na2[KNb24O72H9](2)center dot 120H(2)O (1) has been synthesized and systematically characterized. Visible light photocatalytic H-2 evolution activity was researched with 1 as the visible-light photosensitizer and catalyst, cobaloximes [Co-III(dmgH)(2)pyCl] as the co-catalysts, and triethylamine (TEA) as the sacrificial electron donor.

• 出版日期2012
• 单位东北师范大学