The construction, characterization, Hg(II)-sensing and removal behavior of magnetic core-shell nanospheres loaded with fluorescence "Off-On" probe

作者：Tan Jun^*; Wei Xiaoyan; Chen Jie; Sun Ping; Ouyang Yuxia; Fan Juhong; Liu Rui

来源：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2014, 133: 403-410.

DOI：10.1016/j.saa.2014.05.079

• Hg(II)
• Fe3O4 nanoparticles
• Sensor
• Rhodamine derivative

The present paper constructed and discussed core-shell structured nanospheres grafted with rhodamine based probe for Hg(II) sensing and removal. Electron microscopy images, XRD curves, thermogravimetric analysis and N-2 adsorption/desorption isotherms were used to identify the core-shell structure. The inner core consisted of superparamagnetic Fe3O4 nanoparticles, which made the nanocomposite magnetically removable. The outer shell was constructed with silica molecular sieve which provided large surface area and ordered tunnels for the sensing probe, accelerating analyte adsorption and transportation. The rhodamine based sensing probe emission increased with the increasing Hg(II) concentration, showing emission "Off-On" effect, which could be explained by the structural transformation from a non-emissive one to a highly emissive one. The influence from various metal ions and pH values was also investigated, which suggested this structural transformation could only be triggered by Hg(II), showing high selectivity and linear response. The Hg(II) sensing nanocomposite could be regenerated after usage. The response time was slightly compromised and could be further improved.

• 出版日期2014-12-10
• 单位嘉兴学院