High-Quality 2D Metal-Organic Coordination Network Providing Giant Cavities within Mesoscale Domains

作者：Kuehne Dirk; Klappenberger Florian^*; Decker Regis; Schlickum Uta; Brune Harald; Klyatskaya Svetlana; Ruben Mario; Barth Johannes V

来源：Journal of the American Chemical Society, 2009, 131(11): 3881-+.

DOI：10.1021/ja809946z

A surface-supported open metal-organic nanomesh featuring a 24 nm(2) cavity size and extending to pm domains was fabricated by Co-directed assembly of para-hexaphenyl-dicarbonitrile linker molecules in two dimensions. The metallosupramolecular lattice is thermally robust and resides fully commensurate on the employed Ag(111) substrate as directly verified by high-resolution scanning tunneling microscopy observations.

• 出版日期2009-3-25