Acetatochlorido[2,2 '-(ethane-1,2-diyl)di-1H-benzimidazole]copper(II) monohydrate

作者:Li, Yu-xian; Yang, Huai-xia*; Ding, Ya-nan; Meng, Xiang-ru
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1155-U1045.
DOI:10.1107/S160053681003326X

摘要

In the title complex, [Cu(CH(3)COO)Cl(C(16)H(14)N(4))]center dot H(2)O, the Cu(II) ion is five-coordinated by two N atoms from a 2,2'(ethane-1,2-diyl) di-1H-benzimidazole ligand, two O atoms from a chelating acetate ligand and one terminal monodentate Cl atom in a distorted square-pyramidal geometry. In the crystal, adjacent molecules are linked through O-H center dot center dot center dot Cl, N-H center dot center dot center dot Cl, N-H center dot center dot center dot O and O-H center dot center dot center dot O hydrogen bonds into a three-dimensional network.