A Green and Facile Synthesis of Ordered Mesoporous Nanosilica Using Coal Fly Ash

作者：Yan Feng; Jiang Jianguo; Tian Sicong; Liu Zongwen; Shi Jeffrey; Li Kaimin; Chen Xuejing; Xu Yiwen

来源：ACS Sustainable Chemistry and Engineering, 2016, 4(9): 4654-4661.

DOI：10.1021/acssuschemeng.6b00793

• Coal fly ash
• Mesoporous nanosilica
• Alkali-dissolution process
• Twice-carbonation process
• MCM-41
• Carbon utilization

Ordered mesoporous materials have attracted much attention owing to their superior structural properties. In this work, we develop a green and facile method to convert coal fly ash, a cheap, abundant, and silicon-rich industrial waste, into highly ordered mesoporous nanosilica. An energy efficient technique, the alkali-dissolution process, was systematically studied for the extraction of silica from waste materials, instead of the conventional alkaline fusion method. The extraction efficiency of silica could reach up to 46.62% within 0.5 h at 110 degrees C in 25 wt % sodium hydroxide solution, and the liquid-solid ratio was reduced to 1.5:1. Subsequently, simulated flue gas was introduced to precipitate the nanosilica with the assistance of a surfactant through a twice-carbonation process. A series of characterization techniques confirmed that the synthetic nanosilica (SiO2-0.16) has a high purity (99.35%), high surface area (1,157 m(2) g(-1)), large pore volume (0.95 cm(3) g(-1)), and a highly ordered hexagonal mesostructure (2.88 nm), similar to the characteristics of the material derived from silicon alkoxide. This strategy significantly decreased the energy consumption and shortened the synthesis process through the utilization of flue gas and is thus an effective and scalable approach for the synthesis of ordered mesoporous nanosilica from coal fly ash.

• 出版日期2016-9
• 单位清华大学