A Mn(II) coordination polymer from a polycarboxylate-containing ligand: synthesis, structural characterization, and properties

作者：Zhu, Xiao-Hong^*; Cheng, Xiao-Chun; Qian, Yun-Hua

来源：Zeitschrift Fur Naturforschung Section B-a Journal of Chemical Sciences, 2017, 72(12): 937-940.

DOI：10.1515/znb-2017-0104

• coordination polymer
• magnetic interaction
• Mn(II)
• structural characterization

The neutral, four-fold protonated pyridine-3,5-dicarbox(3,5-dicarboxylatoanilide) (H4L) reacts with Mn(II) salts under hydrothermal conditions to yield a new complex: [Mn-2(L)(H2O)(2)]center dot H2O (1), which has been characterized by single crystal X-ray diffraction, infrared spectroscopy, and elemental and thermogravimetric analyses. Complex 1 exhibits a binodal (4,8)-connected 3D framework with flu (4(12).6(12).8(4))(4(6))(2) topology. The magnetic properties of 1 were investigated.

• 出版日期2017-12
• 单位淮阴工学院