Low-temperature domain wall pinning in titanomagnetite: Quantitative modeling of multidomain first-order reversal curve diagrams and AC susceptibility

作者：Church Nathan^*; Feinberg Joshua M; Harrison Richard

来源：Geochemistry Geophysics Geosystems, 2011, 12(7): Q07Z27.

DOI：10.1029/2011GC003538

• FORC
• domain wall
• low temperature
• pinning
• susceptibility
• titanomagnetite

Domain wall pinning in titanomagnetite has been investigated at low temperatures using first-order reversal curve (FORC) diagrams, AC magnetic susceptibility, and Lorentz transmission electron microscopy. A discontinuous transition from a low-coercivity extrinsic pinning regime to a high-coercivity intrinsic pinning regime is evident in low-temperature FORC diagrams on cooling from 100 to 50 K. Intrinsic pinning is characterized by a "crescent moon" FORC distribution with narrow coercivity distribution centered on 10-20 mT. This crescent-shaped FORC distribution is reproduced using a modification of Neel's (1955) one-dimensional theory of domain wall pinning in a random field. The pinning transition coincides with a thermally activated relaxation process (activation energy 0.13 +/- 0.01 eV), attributed to electron hopping. The relaxation and intrinsic pinning are explained as a magnetoelastic aftereffect caused by enhancement of magnetocrystalline anisotropy due to rearrangement and localization of Fe(2+)-Fe(3+) cations within the domain walls. This study provides experimental verification that Neel's theory is an appropriate quantitative framework for the analysis of FORC diagrams in multidomain titanomagnetite and suggests a potential method for the quantitative unmixing of multidomain signals from FORC diagrams in rock and environmental magnetic studies.

• 出版日期2011-7-28