Nanostructured rutile TiO2 for selective photocatalytic oxidation of aromatic alcohols to aldehydes in water

作者:Yurdakal Sedat; Palmisano Giovanni; Loddo Vittorio; Augugliaro Vincenzo*; Palmisano Leonardo
来源:Journal of the American Chemical Society, 2008, 130(5): 1568-+.
DOI:10.1021/ja709989e

摘要

Selective photocatalytic oxidation of aromatic alcohols to aldehydes was performed in water in the presence of TiO2 rutile photocatalysts that exhibited a low degree of crystallinity. The nanostructured rutile samples, prepared ex TiCl4 at very low temperature, ensured a selectivity toward the aldehyde 3 to 4-fold higher than the commercial rutile tested (Sigma-Aldrich).

  • 出版日期2008-2-6