Aerobic oxidative alpha-arylation of furans with boronic acids via Pd(II)-catalyzed C-C bond cleavage of primary furfuryl alcohols: sustainable access to arylfurans

作者：Huang, Guanghao; Lu, Lin; Jiang, Huanfeng; Yin, Biaolin^*

来源：Chemical communications, 2017, 53(90): 12217-12220.

DOI：10.1039/c7cc07111f

• CARBON-CARBON BONDS
• AZA-PIANCATELLI REARRANGEMENT
• CATALYZED ALLYL TRANSFER
• ACHMATOWICZ REARRANGEMENT
• HOMOALLYL ALCOHOLS
• RETRO-ALLYLATION
• SINGLE BOND
• ACTIVATION
• RHODIUM
• DEAROMATIZATION

Aerobic oxidative alpha-arylation of furans with boronic acids via Pd(II)-catalyzed C-C bond cleavage of primary furfuryl alcohols provides sustainable access to arylfurans. This protocol opens a new avenue for the transformation of readily available furans into other useful compounds.

• 出版日期2017-11-21
• 单位华南理工大学