摘要
A new BODIPY system displaying an intramolecular pi-pi-interaction was synthesized and studied. When the selenium center was oxidized, the substituted phenyl group undergoes pi-pi stacking with one side of the BODIPY core. The oxidized form showed, not only a down-field shift in the NMR peak, but also splitting due to geometrical changes that arise when going from C-s to C-1. The compound was characterized by X-ray diffraction; DFT methods helped elucidate the influence of the unexpected pi-pi stack and its connection to the photophysical properties imparted by the Se oxidation.
- 出版日期2017-3-28