摘要

A new compound, [{Cu-I(bim)}(4){SiW12O40}] (1) (bim=1,2-bis(imidazol-1-yl)ethane), was hydrothermally synthesized and characterized by elemental analyses, IR, TG, and single-crystal X-ray diffraction. Compound 1 is an infinite 1-D chain composed of Cu-bim coordination polymers and [-SiW12O40](4-) polyanions. The electrochemical and electrocatalytic behaviors of 1-modified carbon paste electrode (1-CPE) have been studied.