A [NiFe]hydrogenase model that catalyses the release of hydrogen from formic acid

作者：Nguyen Nga T; Mori Yuki; Matsumoto Takahiro; Yatabe Takeshi; Kabe Ryota; Nakai Hidetaka; Yoon Ki Seok; Ogo Seiji^*

来源：Chemical communications, 2014, 50(87): 13385-13387.

DOI：10.1039/c4cc05911e

We report the decomposition of formic acid to hydrogen and carbon dioxide, catalysed by a NiRu complex originally developed as a [NiFe]hydrogenase model. This is the first example of H-2 evolution, catalysed by a [NiFe]hydrogenase model, which does not require additional energy.

• 出版日期2014-11-11