A Bis(m-phenylene)-32-crown-10/Paraquat [2]Rotaxane

作者:Li Shijun; Zhu Kelong; Zheng Bo; Wen Xianhong; Li Ning; Huang Feihe*
来源:European Journal of Organic Chemistry, 2009, 2009(7): 1053-1057.
DOI:10.1002/ejoc.200801128

摘要

The successful preparation of the first bis(m-phonylene)-32-crown-10/paraquat [2]rotaxane showed unambiguously that psuedorotaxane-type complexation, rather than the taco-complex-type complexation previously observed in the solid state and in solution, exists - in solution for complexation between bis(m-phenylene)-32-crown-10 derivatives and paraquat derivatives.