alpha-Benzoin Oxime in Higher Oxidation State 3d Metal Cluster Chemistry: Structural and Magnetic Study of a New Mn-9(III) Complex

作者：Koumousi Evangelia S; Manos Manolis J; Lampropoulos Christos; Tasiopoulos Anastasios J; Wernsdorfer Wolfgang; Christou George^*; Stamatatos Theocharis C

来源：Inorganic Chemistry, 2010, 49(7): 3077-3079.

DOI：10.1021/ic100178y

The initial employment of alpha-benzoin oxime (bzoxH(2)) in higher oxidation state 3d metal cluster chemistry has provided access to a new enneanuclear Mn-III complex with an unprecedented metal-core topology consisting of two triangular [Mn-3(mu(3)-O2-)(mu-ON)(3)](4+) fragments connected by a linear [Mn-3(mu-ON)(6)](3+) unit. The Mn-9(III) cluster is antiferromagnetically coupled and has an S=3 spin ground state.

• 出版日期2010-4-5