A Set of Olefin Metathesis Catalysts with Extraordinary Stickiness to Silica

作者:Schachner Joerg A; Cabrera Jose; Padilla Robin; Fischer Christoph; van der Schaaf Paul A; Pretot Roger; Rominger Frank; Limbach Michael*
来源:ACS Catalysis, 2011, 1(8): 872-876.
DOI:10.1021/cs2002109

摘要

We report on a series of six new pyridinealkoxide-bridged first and second generation ruthenium carbenes with similar or even higher activity in ring-opening metathesis polymerization (ROMP), cross metathesis (CM), and ring dosing metathesis (RCM) reactions than state-of-the-art catalysts. The new precatalysts show an extraordinarily high stickiness to commercially available silica, which significantly enhances their adsorptive separation from unprocessed reaction mixtures.

  • 出版日期2011-8