Ultrasensitive online SERS detection of structural isomers separated by capillary zone electrophoresis

作者:Negri Pierre; Flaherty Ryan J; Dada Oluwatosin O; Schultz Zachary D*
来源:Chemical communications, 2014, 50(21): 2707-2710.
DOI:10.1039/c3cc49030k

摘要

A mixture of structural isomers was separated and identified at nanomolar concentrations (similar to 100 000 molecules) by incorporating capillary zone electrophoresis (CZE) with a sheath flow surface-enhanced Raman scattering (SERS) detector. Baseline resolution was obtained from three structural isomers of rhodamine using a planar silver SERS substrate, demonstrating the utility of this approach for trace chemical analysis.

  • 出版日期2014