The 13th International Symposium on Relations Between Homogeneous and Heterogeneous Catalysis - An introduction

作者：Somorjai Gabor A^*

来源：Topics in Catalysis, 2008, 48(1-4): 1-7.

DOI：10.1007/s11244-008-9039-6

• catalytic selectivity
• colloid nanoparticles
• oxide-metal interfaces

Over 40 years, there have been major efforts to aim at understanding the properties of surfaces, structure, composition, dynamics on the molecular level and at developing the surface science of heterogeneous and homogeneous catalysis. Since most catalysts (heterogeneous, enzyme and homogeneous) are nanoparticles, colloid synthesis methods were developed to produce monodispersed metal nanoparticles in the 1-10 nm range and controlled shapes to use them as new model catalyst systems in two-dimensional thin film form or deposited in mezoporous three-dimensional oxides. Studies of reaction selectivity in multipath reactions (hydrogenation of benzene, cyclohexene and crotonaldehyde) showed that reaction selectivity depends on both nanoparticle size and shape. The oxide-metal nanoparticle interface was found to be an important catalytic site because of the hot electron flow induced by exothermic reactions like carbon monoxide oxidation.

• 出版日期2008-5