Anthracene derivatives bearing sulfur atoms or selenium atoms as fluorescent chemosensors for Cu2+ and Hg2+ : different selectivity induced from ligand immobilization onto anthracene

作者:Lee Yoon Ju; Seo Dongwon; Kwon Ji Young; Son Guiyoup; Park Min Sun; Choi Yun Hee; Soh Jung Hyun; Lee Ha Na; Lee Kap Duk*; Yoon Juyoung
来源:Tetrahedron, 2006, 62(52): 12340-12344.
DOI:10.1016/j.tet.2006.10.001

摘要

Two new selenium containing anthracene derivatives and two new sulfur containing anthracene derivatives were synthesized as fluorescent chemosensors; for Hg2+ and CU2+. Compound 1 displayed a highly selective chelation enhanced fluorescence quenching (CHEQ) effect only with Cu2+, on the other hand, compounds 3 and 4 displayed highly selective chelation enhanced fluorescence (CHEF) effects only with Hg2+ among the metal ions examined.

  • 出版日期2006-12-25