科研之友
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摘要
Flake-shaped carbonyl iron (FCI) powder was prepared by ball milling spherical carbonyl iron (SCI) powder for 20 h. The thicknesses of the FCI particles were similar to 0.1-0.3 mu m with a diameter of similar to 5-10 mu m. The milling process increased the aspect ratio from similar to 1 for spherical powder to an aspect ratio of similar to 20-100 for flake one. The complex permittivity (epsilon' - j epsilon '') and permeability (mu' - j mu '') were measured by the transmission/reflection method in the frequency range of 2-18 GHz for composites with various weight ratios of SCI and FCI. The results show that all epsilon', epsilon '', mu' and mu '' substantially increased after the milling treatment. Compared to SCI particles, the FCI particles exhibit higher permeability, higher permittivity, and better absorbing properties within the frequency test range. The magnetic loss tangent of FCI composites shows that FCI, with their large shape anisotropy, may have a higher resonance frequency and exceed the Snoek's limit in the gigahertz frequency range. For the 50 wt.% FCI composite with a thickness of 3 mm, the reflection loss at 5.5 GHz reaches -23.0 dB.
- 出版日期2011-4-1
