Dye-sensitized nanocrystalline CdS and ZnS solar cells with different organic dyes

作者：Reda Safenaz M^*; El Sherbieny Said A

来源：Journal of Materials Research, 2010, 25(3): 522-528.

DOI：10.1557/JMR.2010.0077

We have developed dye-sensitized nanocrystalline CdS and ZnS solar cells (DSSCs) based on crystal violet, methylene blue, and fluorescein photosensitizers. Nanocrystalline CdS and ZnS were synthesized by a green synthesis method using starch as the capping agent. Characterization of nanocrystalline CdS and ZnS was carried out by optical absorption and x-ray diffraction. The results indicate that CdS and ZnS prepared by this method may be used as photoelectodes in photo-electro-chemical energy conversion systems. DSSCs have been built and their photocurrent, open-circuit voltage, fill factor, and efficiency have been measured under direct sunlight illumination (1000 Wcm(-2)). The efficiency of the cells made from dye-CdS was much higher than that of the cells made from dye-ZnS. This can be attributed to the particle size effect. Among the prepared dye-sensitized solar cells, a DSSC based on fluorescein dye as the photosensitizer produced the highest overall light solar energy to electricity conversion efficiency.

• 出版日期2010-3