Petroleum Biodegradation Effects on Polar Acidic Compounds and Correlation with Their Corresponded Hydrocarbon Fractions

作者:Angolini Celio F F; Capilla Ramses; Marsaioli Anita J*
来源:Energy & Fuels, 2015, 29(8): 4886-4892.
DOI:10.1021/acs.energyfuels.5b01116

摘要

A set of five oil samples from the same source rock, classified at different levels of biodegradation, was evaluated by high-resolution mass spectrometry (Orbitrap). O-containing acidic compounds from the acidic oil fractions were characterized by determining their molecular formulas. The effects of biodegradation were detected in all O classes and were consistent with the biodegradation of neutral compounds. Additionally, we found a slightly biodegraded sample that contained acidic compounds, biomarkers of a highly biodegraded sample. These results led us to propose a scale of biodegradation using acidic compounds, particularly those containing two oxygen atoms (carboxylic acids).

  • 出版日期2015-8