Water and carbon oxides on monoclinic zirconia: experimental and computational insights

作者:Kouva Sonja; Andersin Jenni; Honkala Karoliina; Lehtonen Juha; Lefferts Leon; Kanervo Jaana*
来源:Physical Chemistry Chemical Physics, 2014, 16(38): 20650-20664.
DOI:10.1039/c4cp02742f

摘要

Zirconium oxide (ZrO2, zirconia) is an interesting catalytic material to be used in biomass conversion, e.g., gasification and reforming. In this work, we show that reducing and hydrating pretreatments affect the surface sites on monoclinic zirconia. The multitechnique approach comprises temperature-programmed surface reactions (TPSR) under CO and CO2 at 100-550 degrees C, in situ DRIFTS investigations of the surface species and density functional theory (DFT) calculations. The key findings of the work are: (1) formates are formed either directly from gas-phase CO on terminal surface hydroxyls or via the linear CO surface species that are found exclusively on the reduced zirconia without water treatment; (2) formates are able to decompose at high temperature either reversibly to CO or reductively to CO2 and H-2 via surface reaction between formates and multicoordinated hydroxyls; and (3) a new weak reversible binding state of CO is found exclusively on ZrO2 that is first reduced and subsequently hydrated.

  • 出版日期2014