Microwave-Assisted Production of Amorphous Calcium Magnesium Phosphate: Study From Co-Precipitation to Sintered Products

作者：Zhou Huan^*; Liu Zhiwei; Shi Xiaohao; Luo Mingzhi; Deng Linhong; Kong Shiqin

来源：International Journal of Applied Ceramic Technology, 2015, 12: E7-E13.

DOI：10.1111/ijac.12361

Under microwave irradiation, agglomerates of nanospherical amorphous calcium magnesium phosphate (ACMP) particles were precipitated from a source solution with Ca2+, Mg2+, and PO43-. These precipitates were achieved when Mg2+ was added no less than three times concentrated of Ca2+. Otherwise, the as-precipitated powder would only be a mixture of brushite (DCPD) and calcium sodium phosphate (CNP) with poor Mg2+ substitution. As compared to the mixture of DCPD and CNP, the as-formed ACMP presented great densification during sintering. Moreover, the as-sintered products were bioactive with final composition of magnesium pyrophosphate (MPP), b-tricalcium phosphate (beta-TCP), and calcium pyrophosphate (CPP).

• 出版日期2015-12
• 单位常州大学