An Easy and Multigram-Scale Synthesis of Versatile AA- and AB-Type m-Terphenylenes as Building Blocks for Kinked Polyphenylenes

作者：Kissel Patrick; Breitler Simon; Reinmueller Viktoria; Lanz Patrick; Federer Lukas; Schlueter A Dieter; Sakamoto Junji^*

来源：European Journal of Organic Chemistry, 2009, 2009(18): 2953-2955.

DOI：10.1002/ejoc.200900263

• Cross-coupling
• Masking
• Macrocycles
• Foldamers
• Polymers

A set of m-terphenylenes having a readily functionalizable hydroxy group as well as either symmetric AA-type or unsymmetric AB-type halide termini have been prepared on a several-gram scale. The synthesis was carried out on the basis of the Suzuki-Miyaura cross-coupling in combination with a TMS masking strategy.

• 出版日期2009-6