Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

作者：Woodall Sean D; Swinburne Adam N; Banik Nidhu lal; Kerridge Andrew; Di Pietro Poppy; Adam Christian; Kaden Peter; Natrajan Louise S^*

来源：Chemical Communications, 2015, 51(25): 5402-5405.

DOI：10.1039/c4cc08718f

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.

• 出版日期2015