New aminomethylphosphines with cyanophenyl substituents at the nitrogen atoms

作者：Spiridonova Yu S; Balueva A S^*; Krivolapov D B; Litvinov I A; Musina E I; Karasik A A; Sinyashin O G

来源：Russian Chemical Bulletin, 2013, 62(11): 2487-2494.

• aminomethylphosphines
• benzonitriles
• 1,5-diaza-3,7-diphosphacyclooctanes
• aminals

A condensation of bis(hydroxymethyl)arylphosphines with 3- and 4-aminobenzonitriles leads to the corresponding 3,7-diaryl-1,5-bis(cyanophenyl)-1,5-diaza-3,7-diphosphacyclo-octanes. Acyclic (aryl) bis[N-(2-cyanophenyl)aminomethyl]phosphines are formed in the case of 2-aminobenzonitrile. Molecular and crystalline structure of the compounds obtained was studied by X-ray diffraction analysis.

• 出版日期2013-11