Azide-based heterobifunctional poly(ethylene oxide)s: NaN3-initiated "living" polymerization of ethylene oxide and chain end functionalizations

作者：Yang Sera; Kim Youn; Kim Hyeong Cheol; Siddique Abu B; Youn Gyusaang; Kim Hyun Jun; Park Hyeon Jong; Lee Jae Yeol; Kim Sehoon; Kim Jungahn^*

来源：Polymer Chemistry, 2016, 7(2): 394-401.

DOI：10.1039/c5py01444a

In this study, sodium azide (NaN3) was employed as a functional anionic initiator to polymerize ethylene oxide in N, N-dimethylformamide (DMF) leading to the production of the reactive polymeric alkoxide. The molecular weights of all products were controlled within the 2800-10 000 g mol(-1) range on the basis of the stoichiometric balance. NaN3-initiated polymerization of ethylene oxide (EO) and chain end functionalization of the resulting alkoxide were found to be a simple and efficient method for synthesizing heterobifunctional PEOs. The reaction route via chain end tosylation of a-azide PEOs was found to yield almost quantitative functionalizations for the synthesis of alpha-azide-omega-tosyl PEO, alpha-azide-omega-thiol PEO, and alpha-amine-omega-thiol PEO (over 98 mol%).

• 出版日期2016