A New Up-conversion Material of Ho3+-Yb3+-Mg2+ Tri-doped TiO2 and Its Applications to Perovskite Solar Cells

作者:Zhang, Zhenlong; Li, Danna; Shi, Wenjia; Liu, Yanyan; Zhang, Yan; Liu, Yuefeng; Gao, Huiping; Mao, Yanli*
来源:Nanoscale Research Letters, 2018, 13(1): 262.
DOI:10.1186/s11671-018-2681-4

摘要

A new up-conversion nanomaterial of Ho3+-Yb3+-Mg2+ tri-doped TiO2 (UC-Mg-TiO2) was designed and synthesized with a sol-gel method. The UC-Mg-TiO2 presented enhanced up-conversion fluorescence by an addition of Mg2+. The UC-Mg-TiO2 was utilized to fabricate perovskite solar cells by forming a thin layer on the electron transfer layer. The results display that the power conversion efficiency of the solar cells based on the electron transfer layer with UC-Mg-TiO2 is improved to 16.3 from 15.2% for those without UC-Mg-TiO2. It is demonstrated that the synthesized UC-Mg-TiO2 can convert the near-infrared light to visible light that perovskite film can absorb to improve the power conversion efficiency of the devices.