Mechanochemical Synthesis and Hydrogen Sorption Properties of Nanocrystalline TiFe

作者:Zadorozhnyy V Yu*; Klyamkin S N; Kaloshkin S D; Zadorozhnyy M Yu; Bermesheva O V
来源:Inorganic Materials, 2011, 47(10): 1081-1086.
DOI:10.1134/S0020168511100232

摘要

The equiatomic intermetallic compound TiFe has been prepared by elemental mechanochemical synthesis in a planetary ball mill from Fe and Ti powders. The structural and phase transformations during synthesis were followed using X-ray diffraction. The reaction of the synthesized compound with hydrogen was studied volumetrically. The results demonstrate that the hydrogen capacity of the mechanochemical TiFe is 1.2 wt % at 2.5 MPa. Its absorption isotherm has an extended plateau in the range 1.6-1.7 MPa at room temperature.

  • 出版日期2011-10