A Solvent-Stable Zinc(II)-Gadolinium(III) Metal-Organic Framework Assembled with Furan-2,5-Dicarboxylic Acid: Synthesis, Crystal Structure and Magnetic Property

作者：Zou, Ji-Yong^*; Li, Ling; You, Sheng-Yong; Liu, Yue-Wei; Cui, Hong-Min; Chen, Kai-Hong; Zhang, Shao-Wei

来源：Journal of Inorganic and Organometallic Polymers and Materials, 2019, 29(2): 359-364.

DOI：10.1007/s10904-018-1006-5

• Zinc(II)-gadolinium(III) MOF
• Furan-2
• 5-dicarboxylic acid
• Solvent-stable
• Antiferromagnetic coupling interaction

A novel three-dimensional 3d-4f metal-organic framework (MOF), {[(CH3)(2)NH2](2)[Zn2Gd2(FDA)(6)(DMF)(2)]2DMF}(n) (Zn-Gd) (H(2)FDA=furan-2,5-dicarboxylic acid) assembled with furan-2,5-dicarboxylic acid has been isolated and characterized by infrared spectra, elemental analysis, thermogravimetric analysis, powder X-ray diffraction and single-crystal X-ray diffraction. Structure analysis indicates this MOF is an interesting three-dimensional 8-connected bcu body centered cubic topological net. Moreover, Zn-Gd MOF shows a tolerance towards moisture and the corresponding solvents, demonstrating the excellent chemical stability. The magnetic property of Zn-Gd MOF suggests a weak antiferromagnetic coupling interaction between adjacent Gd(III) ions in Zn-Gd MOF.

• 出版日期2019-3
• 单位江西省科学院; 中国科学院长春应用化学研究所; 湖南科技大学