A facile and patternable method for the surface modification of carbon nanotube forests using perfluoroarylazides

作者:Pastine Stefan J; Okawa David; Kessler Brian; Rolandi Marco; Llorente Mark; Zettl Alex; Frechet Jean M J*
来源:Journal of the American Chemical Society, 2008, 130(13): 4238-+.
DOI:10.1021/ja8003446

摘要

A facile patterning method for the functionalization of vertically aligned carbon nanotubes; is described. Modification of the surface of nanotube forests with hydrophilic, hydrophobic, or polymerizable small molecules was achieved via UV-triggered attachment of perfluoroarylazides. Multiple functionalizations; of the tube surface can be achieved. Macro- and micropatterning of forest substrates were demonstrated. Superhydrophobic surfaces containing superhydrophilic regions were prepared.

  • 出版日期2008-4-2