A high-nuclearity [Cu6Cd4] antiferromagnet with a supertetrahedral configuration

作者：Zhao, Xiao-Qing^*; Wang, Jin; Bao, Dong-Xu; Xiang, Shuo; Luo, Dai-Bing

来源：Inorganic Chemistry Communications, 2015, 62: 77-80.

DOI：10.1016/j.inoche.2015.10.028

• Pentaerythritol
• Heterometallic coordination cluster
• Supertetrahedral cage
• Antiferromagnet

A heterometallic coordination cluster with the formula of {[Cu6Cd4(HL)(4)(Piv)(8)(H2O)(6)]center dot 4MeOH} (1, H4L = pentaerythritol, Hpiv = pivalic acid) has been synthesized. Compound 1 crystallizes in the tetragonal space group I-4, and consists of a supertetrahedral cage with four Cd(II) and six Cu(II) ions held together by mu(3)-O bridges. Magnetic susceptibility exhibits that compound 1 is an antiferromagnet.

• 出版日期2015-12
• 单位四川农业大学; 四川大学