A new strategy of molecular overcharge protection shuttles for lithium ion batteries

作者:Wang Qing; Zakeeruddin Shaik M; Exnar Ivan; Graetzel Michael
来源:Electrochemistry Communications, 2008, 10(4): 651-654.
DOI:10.1016/j.elecom.2007.11.020

摘要

The conventional strategy of overcharge protection for lithium ion batteries uses redox molecules having oxidation potential higher than the cathodic materials in the electrolyte. Here we propose a novel approach by using redox molecules having reduction potentials lower than the anodic materials. This new approach is successfully demonstrated in TiO2/LiCoO2 and TiO2/LiFePO4 cells by using benzophenone molecule.

  • 出版日期2008-4