A method for introducing organic functional groups on silica surfaces using a functionalized vinylsilane containing polymer

作者:Park Jung Woo; Kim Dong Su; Kim Min Seok; Choi Ji Hwan; Jun Chul Ho*
来源:Polymer Chemistry, 2015, 6(4): 555-560.
DOI:10.1039/c4py01148a

摘要

A new method for introducing robustly bound organic functional groups on silica surfaces is developed. Compared to conventional monomer immobilization procedures, the new vinylsilane-impregnated polymer based protocol can be employed for the preparation of various organic group functionalized silicas that are stable under both acidic and basic conditions. Organic functional groups can be readily introduced by one-step Rh(I)-catalyzed hydroacylation reaction or appended by Suzuki coupling reactions.

  • 出版日期2015