An unprecedented acid/base stable Cu-based metal-organic framework with good catalytic activity for the reduction of 4-nitrophenol

作者：Zhou, Chun-Hui; Wang, Yue-Ming; Jin, Kuang; Ma, Jia-Ju; Hu, Jin-Song^*

来源：Inorganic Chemistry Communications, 2015, 62: 81-84.

DOI：10.1016/j.inoche.2015.10.032

• Metal-organic framework
• Semirigid ligand
• Stability

A new 3D metal-organic framework with pcu topology {[Cu-2(TPOM)(ddpa)(2)]}(n) (1) was synthesized under solvothermal condition by employing flexible tetrakis(4-pyridyloxymethylene) methane (TPOM) and semirigid 4,4'-dicarboxydiphenylamine (H(2)ddpa) as well as Cu(II) ion. Complex 1 exhibits good endurance in acid/base aqueous solutions and a high catalytic activity for the reduction of 4-nitrophenol in excess NaBH4 solution.

• 出版日期2015-12
• 单位安徽理工大学