Novel microporous carbon prepared from discarded clothes as host materials for high performance lithium-sulfur battery

作者：Sun, Xu; Huang, Ying^*; Chen, Menghua; Wang, Yanli; Gao, Xiaogang; Wang, Lihao

来源：Materials Letters, 2018, 232: 122-125.

DOI：10.1016/j.matlet.2018.08.112

• Carbon materials
• Nanoparticles
• Energy storage and conversion

Novel microporous carbon materials (DCMC) with excellent electron conductivity and ultrahigh surface area (1896.9 m(2) g (1)) are successfully prepared from discarded clothes. The porous carbon-encapsulated sulfur composites were synthesized by a feasible melting process and used as host materials for lithium sulfur batteries. Because of the unique microporous, ultrahigh surface area and irregular wrinkled surface coexisting structure, the resulting microporous carbon/sulfur (DCMC/S) composite cathode possesses a good rate capability and long-term cycling performance. The initial discharge capacity of the DCMC2/S composite electrode with 74.3 wt% sulfur content is 1082.6 mAh g (1) at a current rate of 0.2 C. At a higher current rate of 1 C, it possesses excellent cyclic performance and retained a capacity of 422.8 mAh g (1) after 500 cycles with a low capacity fading rate of 0.11% per cycle. The coulombic efficiency remains over 98% during cycling.

• 单位
  西北工业大学