Modification of structural and optical properties of polyvinyl alcohol/polyethylene glycol thin film by laser irradiation

作者：Nouh S A^*; Benthami K; Abutalib M M

来源：Radiation Effects and Defects in Solids-Incorporating Plasma Science and Plasma Technology, 2016, 171(1-2): 87-95.

DOI：10.1080/10420150.2015.1135153

• laser
• polymers
• X-ray
• FTIR
• optical properties

The effect of infrared laser irradiation on the structural and the optical properties of polyvinyl alcohol/polyethylene glycol (PVA/PEG) copolymer has been investigated. Thin films of PVA/PEG (nearly 50 mu m thickness) were irradiated up to 15 J/cm(2) of Ga-As laser pulses of 904 nm, 5W power, and 200-ns pulse duration. The resultant effect of laser irradiation on the structural properties of PVA/PEG has been investigated using X-ray diffraction and Fourier transform infrared spectroscopy (FTIR). Further, the refractive index and the color difference between the exposed samples and the pristine have been studied. FTIR spectroscopy showed that the PVA/PEG samples exhibited degradation under the effect of laser irradiation up to 9 J/cm(2), where crosslinking started and continued until 15 J/cm(2). The refractive index had a minimum value of 1.5020 at 9 J/cm(2), accompanied by a high degree of ordering and maximum value of 1.5640 at 15 J/cm(2), with an increase in disordering character due to the degradation and crosslinking formation inside the sample, respectively. Moreover, the color intensity Delta E was greatly increased with increasing the laser fluence, accompanied by a significant increase in the yellow color component.

• 出版日期2016-5