Dynamic rearrangement of bilayers of porphyrin hetero-dimers at a solid/liquid interface

作者:Lensen Dennis; Habets Thomas; Elemans Johannes A A W*
来源:Chemical Communications, 2014, 50(55): 7291-7294.
DOI:10.1039/c4cc02963a

摘要

STM reveals that self-assembled bilayers of covalently linked Cu-Mn porphyrin dimers can dynamically rearrange at a solid/liquid interface by rapid exchange of molecules between the bilayer and the supernatant, or via a slower two-dimensional translation of the whole top layer.

  • 出版日期2014