A luminescent cadmium itaconate coordination polymer with rare 6(5)8 layer topology from in situ hydrothermal decarboxylation of trans-aconitic acid

作者：Gandolfo Chaun M; LaDuca Robert L^*

来源：Inorganic Chemistry Communications, 2011, 14(7): 1111-1114.

DOI：10.1016/j.inoche.2011.04.001

• Coordination polymer
• Cadmium
• Crystal structure
• Hydrothermal
• In situ ligand synthesis

The luminescent coordination polymer {[Cd(ita)(bpfp)(H2O)]center dot 4H(2)O}(n) (1, ita = itaconate, bpfp = bis(4-pyridylformyl)piperazine) was synthesized via in situ hydrothermal decarboxylation of trans-aconitic acid. [Cd(ita)(H2O)](n) undulating chains with gauche conformation ita ligands are connected into a very rare 4-connected 6(5)8 layered topology by long-spanning bpfp tethering ligands.

• 出版日期2011-7