A new pillared-layer 3D coordination polymer involving in situ generated formate

作者：Xia Yu Pei; Li Yun Wu; Li Da Cheng^*; Du Yu Chang; Yao Qing Xia; Dou Jian Min

来源：Journal of Molecular Structure, 2015, 1081: 362-365.

DOI：10.1016/j.molstruc.2014.10.065

• Coordination polymer
• Pillared-layer
• Fluorescence property

A new Cd-based coordination polymer, [Cd(cpt)(HCOO)](n) (1), has been synthesized from 1-(4-carboxyphenyl)-1,2,4-triazole) ligand (Hcpt). The structure was characterized through X-ray crystallography, elemental analysis, and IR spectrum. Compound 1 presents a three-dimensional (3D) pillared-layer structure constructed by metal-formate layers and cpt(-) ligands. Moreover, the unusual formate anions are generated in situ from the decomposition of DMF precursors. The fluorescence property of 1 in solid state was also researched.

• 出版日期2015-2-5
• 单位聊城大学