Arylation of perfluoroalkyl vinyl sulfoxides via the Heck reaction

作者：Sokolenko Liubov V^*; Yagupolskii Yurii L; Vlasenko Yurii G; Babichenko Liudmila N; Lipetskij Volodimir O; Anselmi Elsa; Magnier Emmanuel

来源：Tetrahedron Letters, 2015, 56(10): 1259-1262.

DOI：10.1016/j.tetlet.2015.01.136

• Heck reaction
• Vinylation
• Cross-coupling
• Palladium
• Vinyl sulfoxides

Heck reactions of perfluoroalkyl vinyl sulfoxides with aryl iodides are studied and palladium(II) acetate is shown to be the most convenient catalyst for this process. New E-1-aryl-2-perfluoroalkylsulfinylethylenes are synthesized. In all cases, by-products without a perfluoroalkylsulfinyl group are formed.

• 出版日期2015-3-4